Growth-microstructure-thermal property relations in AlN thin films

Author:

Song Yiwen1ORCID,Zhang Chi2,Lundh James Spencer1ORCID,Huang Hsien-Lien3,Zheng Yue4,Zhang Yingying2,Park Mingyo4,Mirabito Timothy5,Beaucejour Rossiny6ORCID,Chae Chris3,McIlwaine Nathaniel5,Esteves Giovanni7ORCID,Beechem Thomas E.8ORCID,Moe Craig9ORCID,Dargis Rytis10,Jones Jeremy11,Leach Jacob H.12,Lavelle Robert M.13,Snyder David W.13,Maria Jon-Paul5,Olsson Roy H.6ORCID,Redwing Joan M.5ORCID,Ansari Azadeh4,Hwang Jinwoo3ORCID,Wang Xiaojia2ORCID,Foley Brian M.1,Trolier-McKinstry Susan E.5ORCID,Choi Sukwon1ORCID

Affiliation:

1. Department of Mechanical Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802, USA

2. Department of Mechanical Engineering, University of Minnesota, Minneapolis, Minnesota 55455, USA

3. Department of Materials Science and Engineering, The Ohio State University, Columbus, Ohio 43210, USA

4. School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332, USA

5. Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802, USA

6. Department of Electrical and Systems Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA

7. Microsystems Engineering, Science and Applications (MESA), Sandia National Laboratories, Albuquerque, New Mexico 87123, USA

8. School of Mechanical Engineering and Birck Nanotechnology Center, Purdue University, West Lafayette, Indiana 47904, USA

9. Akoustis, Inc., Canandaigua, New York 14424, USA

10. IQE Plc, Greensboro, North Carolina 27407, USA

11. Nitride Global Inc., Wichita, Kansas 67213, USA

12. Kyma Technologies Inc., Raleigh, North Carolina 27617, USA

13. Electronic Materials and Devices Department, Applied Research Laboratory, University Park, Pennsylvania 16802, USA

Abstract

AlN thin films are enabling significant progress in modern optoelectronics, power electronics, and microelectromechanical systems. The various AlN growth methods and conditions lead to different film microstructures. In this report, phonon scattering mechanisms that impact the cross-plane (κz; along the c-axis) and in-plane (κr; parallel to the c-plane) thermal conductivities of AlN thin films prepared by various synthesis techniques are investigated. In contrast to bulk single crystal AlN with an isotropic thermal conductivity of ∼330 W/m K, a strong anisotropy in the thermal conductivity is observed in the thin films. The κz shows a strong film thickness dependence due to phonon-boundary scattering. Electron microscopy reveals the presence of grain boundaries and dislocations that limit the κr. For instance, oriented films prepared by reactive sputtering possess lateral crystalline grain sizes ranging from 20 to 40 nm that significantly lower the κr to ∼30 W/m K. Simulation results suggest that the self-heating in AlN film bulk acoustic resonators can significantly impact the power handling capability of RF filters. A device employing an oriented film as the active piezoelectric layer shows an ∼2.5× higher device peak temperature as compared to a device based on an epitaxial film.

Funder

National Science Foundation

Air Force Office of Scientific Research

Publisher

AIP Publishing

Subject

General Physics and Astronomy

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