Unimolecular Reactions of Vibrationally Excited CF2ClCHFCH3 and CF2ClCHFCD3: Evidence for the 1,2-FCl Interchange Pathway-Reference-Cited by-同舟云学术

Unimolecular Reactions of Vibrationally Excited CF2ClCHFCH3 and CF2ClCHFCD3: Evidence for the 1,2-FCl Interchange Pathway

Published:2007-03-01 Issue:12 Volume:111 Page:2283-2292
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Burgin M. O.¹,Simmons J. G.¹,Heard G. L.¹,Setser D. W.¹,Holmes B. E.¹

Affiliation:

1. Department of Chemistry, The University of North Carolina at Asheville, One University Heights, Asheville, North Carolina 28804-8511, and Department of Chemistry, Kansas State University, Manhattan, Kansas 66506

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp066722f

Reference39 articles.

1. Unimolecular Rate Constants for HX or DX Elimination (X = F, Cl) from Chemically Activated CF3CH2CH2Cl, C2H5CH2Cl, and C2D5CH2Cl: Threshold Energies for HF and HCl Elimination

2. Rate Constants and Kinetic Isotope Effects for Unimolecular 1,2-HX or DX (X = F or Cl) Elimination from Chemically Activated CF3CFClCH3-d0, -d1, -d2, and -d3

3. 1,2-FCl Rearrangement as an Intermediate Step in the Unimolecular 1,3-HCl Elimination from Chlorofluoropropanes

4. Unimolecular Reaction Kinetics of CF2ClCF2CH3 and CF2ClCF2CD3: Experimental Evidence for a Novel 1,2-FCl Rearrangement Pathway

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1. Calculation of anharmonic effects for the unimolecular dissociation of CF3XCF2CH3 (X = Cl, Br) and CF3XCF2CD3 (X = Cl, Br);Chemical Physics Letters;2019-12

2. Analysis of the Five Unimolecular Reaction Pathways of CD2ClCHFCl with Emphasis on CD2Cl(F)C: and CD2Cl(Cl)C: Formed by 1,1-HCl and 1,1-HF Elimination;The Journal of Physical Chemistry A;2018-09-28

3. Computational study of the threshold energy for the 1,2-interchange of X and R (X, R = halogens, pseudohalogens, and monovalent hydrocarbon groups) on CH2XCH2R;Canadian Journal of Chemistry;2016-12

4. Effects of CF3 and CH3 Groups on the Threshold Energy for the Unimolecular Interchange Reaction of Cl- and F-Atoms in CF3CHFCH2Cl and CH3CHFCH2Cl;The Journal of Physical Chemistry A;2014-04-09

5. Unimolecular Isomerization of CH2FCD2Cl via the Interchange of Cl and F Atoms: Assignment of the Threshold Energy to the 1,2-Dyotropic Rearrangement;The Journal of Physical Chemistry A;2013-07-26