Rate Constants and Kinetic Isotope Effects for Unimolecular 1,2-HX or DX (X = F or Cl) Elimination from Chemically Activated CF3CFClCH3-d0, -d1, -d2, and -d3-Reference-Cited by-同舟云学术

Rate Constants and Kinetic Isotope Effects for Unimolecular 1,2-HX or DX (X = F or Cl) Elimination from Chemically Activated CF3CFClCH3-d0, -d1, -d2, and -d3

Published:2005-10-19 Issue:4 Volume:110 Page:1506-1517
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Zhu Li¹,Simmons J. G.¹,Burgin M. O.¹,Setser D. W.¹,Holmes B. E.¹

Affiliation:

1. Department of Chemistry, The University of North Carolina at Asheville, One University Heights, Asheville, North Carolina 28804-8511

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp053233r

Reference45 articles.

1. Threshold energies and substituent effects for unimolecular elimination of hydrogen chloride (deuterium chloride) and hydrogen fluoride (deuterium fluoride) from chemically activated 1,1-difluoro-1-chloroethane and 1,1-difluoro-1-chloro-2,2,2-trideuterioethane

2. Substituent Effects and Threshold Energies for the Unimolecular Elimination of HCl (DCl) and HF (DF) from Chemically Activated CFCl2CH3 and CFCl2CD3

3. Theoretical calculations of product percentage yields for the thermal decomposition of 2-chloro-1,1-difluoroethane

4. Threshold Energy and Unimolecular Rate Constant for Elimination of HF from Chemically Activated CF3CF2CH3: Effect of the CF3 Substituent on the α-Carbon

5. Threshold Energies and Unimolecular Rate Constants for Elimination of HF from Chemically Activated CF3CH2CH3 and CF3CH2CF3: Effect of CH3 and CF3 Substituents at the β-Carbon and Implications about the Transition State

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