Threshold Energy and Unimolecular Rate Constant for Elimination of HF from Chemically Activated CF3CF2CH3: Effect of the CF3 Substituent on the α-Carbon-Reference-Cited by-同舟云学术

Threshold Energy and Unimolecular Rate Constant for Elimination of HF from Chemically Activated CF3CF2CH3: Effect of the CF3 Substituent on the α-Carbon

Published:1997-02-01 Issue:7 Volume:101 Page:1334-1337
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

McDoniel J. Bridget¹,Holmes Bert E.¹

Affiliation:

1. Department of Chemistry, Lyon College, Batesville, Arkansas 72501

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp963032a

Reference31 articles.

1. Threshold energies and substituent effects for unimolecular elimination of hydrogen chloride (deuterium chloride) and hydrogen fluoride (deuterium fluoride) from chemically activated 1,1-difluoro-1-chloroethane and 1,1-difluoro-1-chloro-2,2,2-trideuterioethane

2. Substituent Effects and Threshold Energies for the Unimolecular Elimination of HCl (DCl) and HF (DF) from Chemically Activated CFCl2CH3 and CFCl2CD3

3. Nonequilibrium unimolecular reactions and collisional deactivation of chemically activated fluoroethane and 1,1,1-trifluoroethane

4. Shock tube pyrolyses. Part I. The thermal decomposition of isopropyl chloride, ethyl fluoride, and n-propyl fluoride

5. Hydrogen fluoride and deuterium fluoride elimination reactions of chemically activated 1,1,1-trideuterio-2,2-difluoroethane, 1,1-difluoroethane, and 1,1,1-trideuterio-2-fluoroethane

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1. Unimolecular Reactions of CF2ClCFClCH2F and CF2ClCF2CH2Cl: Observation of ClF Interchange;The Journal of Physical Chemistry A;2008-11-05

2. Mixed Quantum-Classical Reaction Path Dynamics of C2H5F → C2H4 + HF;The Journal of Physical Chemistry A;2008-10-25

3. Mechanism of G-protein Activation by Rhodopsin;Photochemistry and Photobiology;2006

4. Unimolecular Rate Constants, Kinetic Isotope Effects and Threshold Energies for FH and FD Elimination from CF3CHFCH3 and CF3CHFCD3;The Journal of Physical Chemistry A;2005-11-03

5. Rate Constants and Kinetic Isotope Effects for Unimolecular 1,2-HX or DX (X = F or Cl) Elimination from Chemically Activated CF3CFClCH3-d0, -d1, -d2, and -d3;The Journal of Physical Chemistry A;2005-10-19