Unimolecular Reactions of CF2ClCFClCH2F and CF2ClCF2CH2Cl: Observation of ClF Interchange-Reference-Cited by-同舟云学术

Unimolecular Reactions of CF2ClCFClCH2F and CF2ClCF2CH2Cl: Observation of ClF Interchange

Published:2008-11-05 Issue:47 Volume:112 Page:12117-12124
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Zaluzhna Oksana¹,Simmons Jay G.¹,Setser D. W.¹,Holmes Bert E.¹

Affiliation:

1. Department of Chemistry, University of North Carolina—Asheville, One University Heights, Asheville, North Carolina 28804-8511, and Department of Chemistry, Kansas State University, Manhattan, Kansas 66506

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp806732e

Reference27 articles.

1. Rate Constants and Kinetic Isotope Effects for Unimolecular 1,2-HX or DX (X = F or Cl) Elimination from Chemically Activated CF3CFClCH3-d0, -d1, -d2, and -d3

2. Unimolecular Elimination of HF and HCl from Chemically Activated CF 3CFClCH 2Cl

3. Unimolecular Reactions of Vibrationally Excited CF2ClCHFCH3 and CF2ClCHFCD3: Evidence for the 1,2-FCl Interchange Pathway

4. b⟨E(CF2ClCF2CH3)⟩ was reduced from 98 to 96 kcal mol−1in (3c), which lowers theE0values of (3a) by 1 kcal mol−1for CF2ClCF2CH3.

5. Unimolecular Reactions of Chemically Activated CF2BrCF2CH3 and CF2BrCF2CD3: Evidence for 1,2-FBr Interchange

Cited by 12 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Computational study of the threshold energy for the 1,2-interchange of X and R (X, R = halogens, pseudohalogens, and monovalent hydrocarbon groups) on CH2XCH2R;Canadian Journal of Chemistry;2016-12

2. Effects of CF3 and CH3 Groups on the Threshold Energy for the Unimolecular Interchange Reaction of Cl- and F-Atoms in CF3CHFCH2Cl and CH3CHFCH2Cl;The Journal of Physical Chemistry A;2014-04-09

3. Unimolecular Isomerization of CH2FCD2Cl via the Interchange of Cl and F Atoms: Assignment of the Threshold Energy to the 1,2-Dyotropic Rearrangement;The Journal of Physical Chemistry A;2013-07-26

4. Studies of 1,2-Dihalo Shifts in Carbon–Carbon, Carbon–Silicon, and Silicon–Silicon Systems: A Computational Study;Organometallics;2012-11-06

5. Isomerisation of CF2ClCH2Cl and CFCl2CH2F by Interchange of Cl and F Atoms with Analysis of the Unimolecular Reactions of Both Molecules;ChemPhysChem;2012-01-27