Unimolecular Isomerization of CH2FCD2Cl via the Interchange of Cl and F Atoms: Assignment of the Threshold Energy to the 1,2-Dyotropic Rearrangement-Reference-Cited by-同舟云学术

Unimolecular Isomerization of CH2FCD2Cl via the Interchange of Cl and F Atoms: Assignment of the Threshold Energy to the 1,2-Dyotropic Rearrangement

Published:2013-07-26 Issue:31 Volume:117 Page:6717-6723
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Tucker Mary K.¹,Rossabi Samuel M.¹,McClintock Corey E.¹,Heard George L.¹,Setser D. W.¹,Holmes Bert E.¹

Affiliation:

1. Department of Chemistry, University of North Carolina—Asheville, One University Heights, Asheville, North Carolina 28804-8511, and Kansas State University, Manhattan, Kansas 66506, United States

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp4032767

Reference31 articles.

1. Isomerisation of CF2ClCH2Cl and CFCl2CH2F by Interchange of Cl and F Atoms with Analysis of the Unimolecular Reactions of Both Molecules

2. Unimolecular Reactions in the CF3CH2Cl ↔ CF2ClCH2F System: Isomerization by Interchange of Cl and F Atoms

3. A computational study of the threshold energies of the 1,2-FCl interchange reaction of chlorofluoroethanes

4. Theoretical calculations of product percentage yields for the thermal decomposition of 2-chloro-1,1-difluoroethane

5. Anomalous elimination of HCl from 2-chloro-1,1-difluoroethane. Likely involvement of a 1,2-FCl interchange mechanism

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