Unimolecular Rate Constants, Kinetic Isotope Effects and Threshold Energies for FH and FD Elimination from CF3CHFCH3 and CF3CHFCD3-Reference-Cited by-同舟云学术

Unimolecular Rate Constants, Kinetic Isotope Effects and Threshold Energies for FH and FD Elimination from CF3CHFCH3 and CF3CHFCD3

Published:2005-11-03 Issue:47 Volume:109 Page:10726-10733
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Holmes Doug A.¹,Holmes Bert E.¹

Affiliation:

1. Department of Chemistry, University of North Carolina at Asheville, One University Heights, Asheville, North Carolina 28804-8511, and Department of Chemistry, Lyon College, Batesville, Arkansas 72501

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp054536o

Reference23 articles.

1. Threshold Energies and Unimolecular Rate Constants for Elimination of HF from Chemically Activated CF3CH2CH3 and CF3CH2CF3: Effect of CH3 and CF3 Substituents at the β-Carbon and Implications about the Transition State

2. Threshold Energy and Unimolecular Rate Constant for Elimination of HF from Chemically Activated CF3CF2CH3: Effect of the CF3 Substituent on the α-Carbon

3. Unimolecular Reaction Kinetics of CF2ClCF2CH3 and CF2ClCF2CD3: Experimental Evidence for a Novel 1,2-FCl Rearrangement Pathway

4. 1,2-FCl Rearrangement as an Intermediate Step in the Unimolecular 1,3-HCl Elimination from Chlorofluoropropanes

5. Unimolecular Rate Constants for HX or DX Elimination (X = F, Cl) from Chemically Activated CF3CH2CH2Cl, C2H5CH2Cl, and C2D5CH2Cl: Threshold Energies for HF and HCl Elimination

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1. Calculation of anharmonic effects for the unimolecular dissociation of CF3XCF2CH3 (X = Cl, Br) and CF3XCF2CD3 (X = Cl, Br);Chemical Physics Letters;2019-12

2. Unimolecular Reactions of 1,1,1-Trichloroethane, 1,1,1-Trichloropropane, and 3,3,3-Trifluoro-1,1,1-trichloropropane: Determination of Threshold Energies by Chemical Activation;The Journal of Physical Chemistry A;2014-09-24

3. Isomerization of Neopentyl Chloride and Neopentyl Bromide by a 1,2-Interchange of a Halogen Atom and a Methyl Group;The Journal of Physical Chemistry A;2010-09-01

4. Unimolecular Rate Constant and Threshold Energy for the HF Elimination from Chemically Activated CF3CHFCF3;The Journal of Physical Chemistry A;2010-06-10

5. Unimolecular Reactions of CH2BrCH2Br, CH2BrCH2Cl, and CH2BrCD2Cl: Identification of the Cl−Br Interchange Reaction;The Journal of Physical Chemistry A;2010-03-10