Unimolecular Rate Constants for HX or DX Elimination (X = F, Cl) from Chemically Activated CF3CH2CH2Cl, C2H5CH2Cl, and C2D5CH2Cl: Threshold Energies for HF and HCl Elimination
Author:
Affiliation:
1. Lyon College, 2300 Highland Road, Batesville, Arkansas 72503-2317, and University of North Carolina at Asheville, One University Heights, Asheville, North Carolina 28804-8511
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp040735g
Reference67 articles.
1. Threshold Energies and Unimolecular Rate Constants for Elimination of HF from Chemically Activated CF3CH2CH3 and CF3CH2CF3: Effect of CH3 and CF3 Substituents at the β-Carbon and Implications about the Transition State
2. Threshold Energy and Unimolecular Rate Constant for Elimination of HF from Chemically Activated CF3CF2CH3: Effect of the CF3 Substituent on the α-Carbon
3. Unimolecular Reaction Kinetics of CF2ClCF2CH3 and CF2ClCF2CD3: Experimental Evidence for a Novel 1,2-FCl Rearrangement Pathway
4. 1,2-FCl Rearrangement as an Intermediate Step in the Unimolecular 1,3-HCl Elimination from Chlorofluoropropanes
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