Threshold Energies and Unimolecular Rate Constants for Elimination of HF from Chemically Activated CF3CH2CH3 and CF3CH2CF3: Effect of CH3 and CF3 Substituents at the β-Carbon and Implications about the Transition State-Reference-Cited by-同舟云学术

Threshold Energies and Unimolecular Rate Constants for Elimination of HF from Chemically Activated CF3CH2CH3 and CF3CH2CF3: Effect of CH3 and CF3 Substituents at the β-Carbon and Implications about the Transition State

Published:1998-02-18 Issue:28 Volume:102 Page:5393-5397
ISSN:1089-5639
Container-title:The Journal of Physical Chemistry A
language:en
Short-container-title:J. Phys. Chem. A

Author:

Ferguson Heather A.¹,Ferguson John D.¹,Holmes Bert E.¹

Affiliation:

1. Department of Chemistry, Lyon College, Batesville, Arkansas 72501

Publisher

American Chemical Society (ACS)

Subject

Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jp972854k

Reference30 articles.

1. Stereochemistry of the four-centered gas-phase dehydrohalogenation reaction

2. Threshold energies and substituent effects for unimolecular elimination of hydrogen chloride (deuterium chloride) and hydrogen fluoride (deuterium fluoride) from chemically activated 1,1-difluoro-1-chloroethane and 1,1-difluoro-1-chloro-2,2,2-trideuterioethane

3. Unimolecular rate constants for chemically activated 1,1,1-trifluoro-2-chloroethane: a competitive three-channel system

4. Substituent Effects and Threshold Energies for the Unimolecular Elimination of HCl (DCl) and HF (DF) from Chemically Activated CFCl2CH3 and CFCl2CD3

5. Threshold Energy and Unimolecular Rate Constant for Elimination of HF from Chemically Activated CF3CF2CH3: Effect of the CF3 Substituent on the α-Carbon

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1. Mixed Quantum-Classical Reaction Path Dynamics of C2H5F → C2H4 + HF;The Journal of Physical Chemistry A;2008-10-25

2. Charge exchange, surface-induced dissociation and reactions of doubly charged molecular ions SF42+ upon impact on a stainless steel surface: A comparison with surface-induced dissociation of singly charged SF4+ molecular ions;International Journal of Mass Spectrometry;2008-09

3. Unimolecular Rate Constants, Kinetic Isotope Effects and Threshold Energies for FH and FD Elimination from CF3CHFCH3 and CF3CHFCD3;The Journal of Physical Chemistry A;2005-11-03

4. Rate Constants and Kinetic Isotope Effects for Unimolecular 1,2-HX or DX (X = F or Cl) Elimination from Chemically Activated CF3CFClCH3-d0, -d1, -d2, and -d3;The Journal of Physical Chemistry A;2005-10-19

5. Unimolecular Rate Constants for HX or DX Elimination (X = F, Cl) from Chemically Activated CF3CH2CH2Cl, C2H5CH2Cl, and C2D5CH2Cl: Threshold Energies for HF and HCl Elimination;The Journal of Physical Chemistry A;2005-04-30