Unimolecular Reactions of 1,1,1-Trichloroethane, 1,1,1-Trichloropropane, and 3,3,3-Trifluoro-1,1,1-trichloropropane: Determination of Threshold Energies by Chemical Activation
Author:
Affiliation:
1. Department of Chemistry, University of North Carolina Asheville, One University Heights, Asheville, North Carolina 28804-8511, United States
2. Kansas State University, Manhattan, Kansas 66506, United States
Funder
Directorate for Biological Sciences
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp507788v
Reference47 articles.
1. The Pyrolysis of 1,1,1-Trichloroethane1
2. Ab initio, DFT and transition state theory calculations on 1,2-HF, HCI and CIF elimination reactions from CH2F–CH2Cl
3. Unimolecular Rate Constants for HX or DX Elimination (X = F, Cl) from Chemically Activated CF3CH2CH2Cl, C2H5CH2Cl, and C2D5CH2Cl: Threshold Energies for HF and HCl Elimination
4. Die Kinetik des thermischen Zerfalls von 1,1-Dichloräthan
5. The Thermal Unimolecular Decompositions of CH3CD2Cl, CD3CD2Cl, and CH3CHCl2
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1. Experimental and Computational Studies of Unimolecular 1,1-HX (X = F, Cl) Elimination Reactions of C2D5CHFCl: Role of Carbene:HF and HCl Adducts in the Exit Channel of RCHFCl and RCHCl2 Reactions;The Journal of Physical Chemistry A;2019-03-06
2. Carbocation stability as predictor for electrophilic addition of HCl to chlorinated ethenes and propenes in the gas phase;Journal of Physical Organic Chemistry;2018-12-26
3. Analysis of the Five Unimolecular Reaction Pathways of CD2ClCHFCl with Emphasis on CD2Cl(F)C: and CD2Cl(Cl)C: Formed by 1,1-HCl and 1,1-HF Elimination;The Journal of Physical Chemistry A;2018-09-28
4. Chemical Activation Study of the Unimolecular Reactions of CD3CD2CHCl2 and CHCl2CHCl2 with Analysis of the 1,1-HCl Elimination Pathway;The Journal of Physical Chemistry A;2016-10-18
5. Topological analysis of transition states of the concerted molecular decomposition of haloalkanes and alcohols with HHal and HOH elimination;Russian Chemical Bulletin;2016-10
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