Chemical Activation Study of the Unimolecular Reactions of CD3CD2CHCl2 and CHCl2CHCl2 with Analysis of the 1,1-HCl Elimination Pathway
Author:
Affiliation:
1. Department of Chemistry, University of North Carolina—Asheville, One University Heights, Asheville, North Carolina 28804-8511, United States
2. Department of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States
Funder
Division of Chemistry
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.jpca.6b07368
Reference39 articles.
1. Robinson, P. J.; Holbrook, K. A.Unimolecular Reactions;Wiley-Interscience,New York, 1972; Tables 7.20, 7.21. 7.22, pp217–226.
2. Unimolecular Rate Constants for HX or DX Elimination (X = F, Cl) from Chemically Activated CF3CH2CH2Cl, C2H5CH2Cl, and C2D5CH2Cl: Threshold Energies for HF and HCl Elimination
3. Unimolecular Reactions of 1,1,1-Trichloroethane, 1,1,1-Trichloropropane, and 3,3,3-Trifluoro-1,1,1-trichloropropane: Determination of Threshold Energies by Chemical Activation
4. Decomposition of vibrationally excited 1,1,1-trideuterio-2,2-difluoroethane
5. Hydrogen fluoride and deuterium fluoride elimination reactions of chemically activated 1,1,1-trideuterio-2,2-difluoroethane, 1,1-difluoroethane, and 1,1,1-trideuterio-2-fluoroethane
Cited by 3 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Unimolecular HBr and HF Elimination Reactions of Vibrationally Excited C2H5CH2Br and C2D5CHFBr: Identification of the 1,1-HBr Elimination Reaction from C2D5CHFBr and Search for the C2D5(F)C:HBr Adduct;The Journal of Physical Chemistry A;2019-09-12
2. Experimental and Computational Studies of Unimolecular 1,1-HX (X = F, Cl) Elimination Reactions of C2D5CHFCl: Role of Carbene:HF and HCl Adducts in the Exit Channel of RCHFCl and RCHCl2 Reactions;The Journal of Physical Chemistry A;2019-03-06
3. Analysis of the Five Unimolecular Reaction Pathways of CD2ClCHFCl with Emphasis on CD2Cl(F)C: and CD2Cl(Cl)C: Formed by 1,1-HCl and 1,1-HF Elimination;The Journal of Physical Chemistry A;2018-09-28
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