Selectivity in the C–H Activation Reaction of CH3OSO2CH3 with [1,2,4-(Me3C)3C5H2]2CeH or [1,2,4-(Me3C)3C5H2][1,2-(Me3C)2-4-(Me2CCH2)C5H2]Ce: To Choose or Not To Choose-Reference-Cited by-同舟云学术

Selectivity in the C–H Activation Reaction of CH3OSO2CH3 with [1,2,4-(Me3C)3C5H2]2CeH or [1,2,4-(Me3C)3C5H2][1,2-(Me3C)2-4-(Me2CCH2)C5H2]Ce: To Choose or Not To Choose

Published:2012-01-20 Issue:3 Volume:31 Page:870-881
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Werkema Evan L.¹,Castro Ludovic²,Maron Laurent²,Eisenstein Odile³,Andersen Richard A.¹

Affiliation:

1. Department of Chemistry and Chemical Sciences Division of Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720-1460, United States

2. LPCNO, Université de Toulouse, INSA, UPS, LPCNO, 135 avenue de Rangueil, F-31077 Toulouse, France, and CNRS, LPCNO, F-31077 Toulouse, France

3. Institut Charles Gerhardt, Université Montpellier 2, CNRS 5253, cc 1501, Place E. Bataillon, F-34095 Montpellier France.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om200842t

Reference39 articles.

1. Hydrogen for Fluorine Exchange in CH4-xFx by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Studies

2. Hydrogen for X-Group Exchange in CH3X (X = Cl, Br, I, OMe, and NMe2) by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism

3. Splitting a C–O bond in dialkylethers with bis(1,2,4-tri-tert-butylcyclopentadienyl)cerium hydride does not occur by a σ-bond metathesis pathway: a combined experimental and DFT computational study

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