Hydrogen for X-Group Exchange in CH3X (X = Cl, Br, I, OMe, and NMe2) by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism

Author:

Werkema Evan L.1,Andersen Richard A.1,Yahia Ahmed1,Maron Laurent1,Eisenstein Odile1

Affiliation:

1. Department of Chemistry, University of California, Berkeley, California 94720-1460, Université de Toulouse, INSA, UPS, LPCNO, 135 Avenue de Rangueil, 31077 Toulouse, France, and CNRS, 31077 Toulouse, France, Institut Charles Gerhardt, Université Montpellier 2, UMR 5253 CNRS-UM2-ENSCM-UM1, Place E. Bataillon, 34095 Montpellier France, and CNRS, Institut Charles Gerhardt, France, and ICSM, UM5257, CEA-CNRS-UM2, Site de Marcoule, BP17171, 30207 Bagnols-sur Cèze, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Reference62 articles.

1. Hydrogen for Fluorine Exchange in CH4-xFx by Monomeric [1,2,4-(Me3C)3C5H2]2CeH:  Experimental and Computational Studies

2. Slayden, S. W.; Liebman, J. F.; Mallard, W. G.InThe Chemistry of Halides, Pseudohalides and Azides, Suppl. D2;Patai, S.; Rappoport, Z., Eds.Wiley:Chichester, 1995; p386.

3. Pankratz, L. B.Thermodynamic Properties of Halides, Bulletin 674, Bureau of Mines; 1984.

4. Reactions of Monomeric [1,2,4-(Me3C)3C5H2]2CeH and CO with or without H2:  An Experimental and Computational Study

5. Reactions of Monomeric [1,2,4-(Me3C)3C5H2]2CeH and CO with or without H2:  An Experimental and Computational Study [J. Am. Chem. Soc. 2007, 129, 2529−2541].

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