Synthesis and molecular structure of pentadienyl complexes of the rare-earth metals-Reference-Cited by-同舟云学术

Synthesis and molecular structure of pentadienyl complexes of the rare-earth metals

Published:2018 Issue:41 Volume:47 Page:14468-14482
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Raeder Jan¹²³⁴,Reiners Matthias¹²³⁴,Baumgarten Robert¹²³⁴,Münster Katharina¹²³⁴,Baabe Dirk¹²³⁴,Freytag Matthias¹²³⁴,Jones Peter G.¹²³⁴,Walter Marc D.¹²³⁴^ORCID

Affiliation:

1. Technische Universität Braunschweig

2. Institut für Anorganische und Analytische Chemie

3. 38106 Braunschweig

4. Germany

Abstract

In combination with small and difficult to reduce rare-earth metals pdl′ undergoes CH-bond activations instead of sterically induced reductions to form dimeric complexes with a unique bridging six-membered metallacycle as the central structural motif.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C8DT03123A

Reference116 articles.

1. A New Type of Organo-Iron Compound

2. Synthesis, Structure, and Reactivity of Organometallic .pi.-Complexes of the Rare Earths in the Oxidation State Ln3+ with Aromatic Ligands

3. CYCLOPENTADIENYL COMPOUNDS OF Sc, Y, La, Ce AND SOME LANTHANIDE ELEMENTS