Hydrogen for Fluorine Exchange in CH4-xFx by Monomeric [1,2,4-(Me3C)3C5H2]2CeH:  Experimental and Computational Studies

Author:

Werkema Evan L.1,Messines Elsa1,Perrin Lionel1,Maron Laurent1,Eisenstein Odile1,Andersen Richard A.1

Affiliation:

1. Contribution from the Chemistry Department and Chemical Sciences Division of Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720, Laboratoire de Physique Quantique, UMR 5626-CNRS, IRSAMC, Université Paul Sabatier, 118 Route de Narbonne, 31064 Toulouse Cedex 04, France, and LSDSMS, (UMR 5636-CNRS), Institut Gerhardt, cc14, Université Montpellier 2, 34095 Montpellier Cedex 5, France

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference40 articles.

1. Slayden, S. W.; Liebman, J. F.; Mallard, W. G. InThe Chemistry ofHalides, Pseudohalides and Azides; Supp D2; Patai, S., Rappoport, Z., Eds.; Wiley:  Chichester 1995; p 386.

2. Catalytic hydrogenolysis of carbon-fluoride bonds: π bond participation mechanism

3. Gas-Phase Reactivity of Lanthanide Cations with Fluorocarbons:  C−F versus C−H and C−C Bond Activation

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