Splitting a C–O bond in dialkylethers with bis(1,2,4-tri-tert-butylcyclopentadienyl)cerium hydride does not occur by a σ-bond metathesis pathway: a combined experimental and DFT computational study-Reference-Cited by-同舟云学术

Splitting a C–O bond in dialkylethers with bis(1,2,4-tri-tert-butylcyclopentadienyl)cerium hydride does not occur by a σ-bond metathesis pathway: a combined experimental and DFT computational study

Published:2010 Issue:10 Volume:34 Page:2189
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Werkema Evan L.,Yahia Ahmed,Maron Laurent,Eisenstein Odile,Andersen Richard A.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2010/NJ/C0NJ00261E

Reference27 articles.

1. Hydrogen for Fluorine Exchange in CH4-xFx by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Studies

2. Hydrogen for X-Group Exchange in CH3X (X = Cl, Br, I, OMe, and NMe2) by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism

3. Facile C–H activation by lutetium–methyl and lutetium–hydride complexes

4. .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds

5. Activation of Ethers and Sulfides by Organolanthanide Hydrides. Molecular Structures of (Cp*2Y)2(.mu.-OCH2CH2O)(THF)2 and (Cp*2Ce)2(.mu.-O)(THF)2

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