High-Quality AlN Grown on Si(111) Substrate by Epitaxial Lateral Overgrowth

Author:

Huang Yingnan12ORCID,Liu Jianxun123,Sun Xiujian12,Zhan Xiaoning12,Sun Qian123ORCID,Gao Hongwei23,Feng Meixin123ORCID,Zhou Yu123,Yang Hui12

Affiliation:

1. School of Nano Technology and Nano Bionics, University of Science and Technology of China, Hefei 230026, China

2. Key Laboratory of Nanodevices and Applications, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, China

3. Guangdong Institute of Semiconductor Micro-Nano Manufacturing Technology, Foshan 528000, China

Abstract

We report on the epitaxial lateral overgrowth (ELO) of high-quality AlN on stripe-patterned Si(111) substrates with various trench widths. By narrowing down the trench and ridge widths of patterned Si substrates, crack-free, 6-micrometer-thick, high-quality AlN films on Si substrates were produced. The full-width-at-half-maximum values of the X-ray-diffraction rocking curves for the AlN (0002) and (101¯2) planes were as low as 260 and 374 arcsec, respectively, corresponding to a record low dislocation density of 1.3 × 109 cm−2. Through the combination of a micro-Raman study and the X-ray diffraction analysis, it was found that narrowing the stripe width from 5 μm to 3 μm can reduce the vertical growth thickness before coalescence, resulting in a large decrease in the internal tensile stress and tilt angle, and, therefore, better suppression in the cracks and dislocations of the ELO–AlN. This work paves the way for the fabrication of high-performance Al(Ga)N-based thin-film devices such as ultraviolet light-emitting diodes and AlN bulk acoustic resonators grown on Si.

Funder

National Key R&D Program of China

Guangdong Province Key-Area R&D Program

Natural Science Foundation of China

Jiangxi Double Thousand Plan

Jiangxi Science and Technology Program

Strategic Priority Research Program of CAS

Key Research Program of Frontier Sciences, CAS

Bureau of International Cooperation, CAS

Key R&D Program of Jiangsu Province

Suzhou Science and Technology Program

Publisher

MDPI AG

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering

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