The β-phosphorus hyperfine coupling constant in nitroxide: part 3: titration of water by electron paramagnetic resonance

Author:

Audran Gérard12345,Bosco Lionel12345,Brémond Paul12345,Butscher Teddy12345,Franconi Jean-Michel678910,Marque Sylvain R. A.12345,Mellet Philippe678910,Parzy Elodie678910,Santelli Maurice12345,Thiaudière Eric678910

Affiliation:

1. Aix-Marseille Université

2. CNRS-UMR 7273

3. ICR

4. case 541

5. 13397 Marseille Cedex 20

6. CRMSB

7. CNRS-UMR-5536

8. Université Victor Segalen Bordeaux 2

9. 33076 Bordeaux Cedex

10. France

Abstract

Titration of a few percent of water in an organic solvent is possible due to a large difference in aP.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference36 articles.

1. G. Likhtenshtein , J.Yamauchi, S.Nakatsuji, A. I.Smirnov and R.Tamura, Nitroxides: Applications in Chemistry, Biomedicine, and Materials Science, Wiley-VCH, 2008, and references therein

2. Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds, ed. R. Hicks, Wiley, Hoboken, 2010, pp. 173–229, and references therein

3. Nitroxides with two pK values—useful spin probes for pH monitoring within a broad range

4. V. Belle , S.Rouger, S.Costanzo, A.Longhi and A.Fournel, Assessing Structures and Conformations of Intrinsically Disordered Proteins, ed. V. N. Uversky, Wiley, Hoboken, 2009, and references cited therein

5. New Concepts in Molecular Imaging: Non-Invasive MRI Spotting of Proteolysis Using an Overhauser Effect Switch

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