The β-phosphorus hyperfine coupling constant in nitroxides: 6. Solvent effects in non-cyclic nitroxides-Reference-Cited by-同舟云学术

The β-phosphorus hyperfine coupling constant in nitroxides: 6. Solvent effects in non-cyclic nitroxides

Published:2016 Issue:15 Volume:14 Page:3729-3743
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Audran Gérard¹²³⁴⁵,Bosco Lionel¹²³⁴⁵,Nkolo Paulin¹²³⁴⁵,Bikanga Raphael⁶⁷⁸⁹,Brémond Paul¹²³⁴⁵,Butscher Teddy¹²³⁴⁵,Marque Sylvain R. A.¹²³⁴⁵

Affiliation:

1. Aix-Marseille Université

2. CNRS-UMR 7273

3. ICR

4. 13397 Marseille Cedex 20

5. France

6. Université des Sciences et Technique de Masuku

7. Laboratoire de Substances Naturelles et des Syntheses Organometalliques

8. B.P. 493 Franceville

9. Gabon

Abstract

The impact of the solvent on a_P and a_N decreases strikingly upon increasing both the bulkiness and the polarity of the substituents around the nitroxyl moiety.

Funder

Agence Nationale de la Recherche

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C6OB00359A

Reference41 articles.

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2. Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds, ed. R. Hicks, Wiley, Hoboken, 2010, pp. 173–229, and references therein

3. Nitroxides with two pK values—useful spin probes for pH monitoring within a broad range

4. V. Belle , S.Rouger, S.Costanzo, A.Longhi and A.Fournel, Assessing Structures and Conformations of Intrinsically Disordered Proteins, ed. V. N. Uversky, Wiley, Hoboken, 2009, and references cited therein

5. New Concepts in Molecular Imaging: Non-Invasive MRI Spotting of Proteolysis Using an Overhauser Effect Switch

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