β-Phosphorus hyperfine coupling constant in nitroxides: 5. Solvent effect-Reference-Cited by-同舟云学术

β-Phosphorus hyperfine coupling constant in nitroxides: 5. Solvent effect

Published:2016 Issue:7 Volume:6 Page:5653-5670
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Audran Gérard¹²³⁴⁵,Bosco Lionel¹²³⁴⁵,Brémond Paul¹²³⁴⁵,Butscher Teddy¹²³⁴⁵,Franconi Jean-Michel⁶⁷⁸⁹⁵,Kabitaev Kuanysh¹²³⁴⁵,Marque Sylvain R. A.¹²³⁴⁵,Mellet Philippe⁶⁷⁸⁹⁵,Parzy Elodie⁶⁷⁸⁹⁵,Santelli Maurice¹²³⁴⁵,Thiaudière Eric⁶⁷⁸⁹⁵,Viel Stéphane¹²³⁴⁵^ORCID

Affiliation:

1. Aix-Marseille Université

2. CNRS-UMR 7273

3. ICR

4. 13397 Marseille Cedex 20

5. France

6. CRMSB

7. CNRS-UMR-5536

8. Université Victor Segalen Bordeaux 2

9. 33076 Bordeaux Cedex

Abstract

a _N and a_P of β-phosphorylated 5-membered ring nitroxides are sensitive to the polarity/polarisability π*, the structuredness of the solvent c, and to the hydrogen bond donating α properties of the solvent.

Funder

Agence Nationale de la Recherche

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA23521A

Reference44 articles.

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2. Stable Radicals: Fundamentals and Applied Aspects of Odd-Electron Compounds, ed. R. Hicks, Wiley, Hoboken, 2010, pp. 173–229, and references therein

3. Nitroxides with two pK values—useful spin probes for pH monitoring within a broad range

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5. New Concepts in Molecular Imaging: Non-Invasive MRI Spotting of Proteolysis Using an Overhauser Effect Switch

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