Nanoscale solvent organization in metal–organic framework ZIF-8 probed by EPR of flexible β-phosphorylated nitroxides-Reference-Cited by-同舟云学术

Nanoscale solvent organization in metal–organic framework ZIF-8 probed by EPR of flexible β-phosphorylated nitroxides

Published:2024 Issue:14 Volume:15 Page:5268-5276
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Poryvaev Artem S.¹,Efremov Aleksandr A.¹²,Alimov Dmitry V.¹²,Smirnova Kristina A.¹²^ORCID,Polyukhov Daniil M.¹,Sagdeev Renad Z.¹,Jacoutot Samuel³,Marque Sylvain R. A.³^ORCID,Fedin Matvey V.¹²^ORCID

Affiliation:

1. International Tomography Center SB RAS, Novosibirsk, 630090, Russia

2. Novosibirsk State University, Novosibirsk, 630090, Russia

3. Aix Marseille University, CNRS, UMR, Avenue Escadrille Normandie-Niemen, 7273 Marseille, 13397 CEDEX 20, France

Abstract

Molecules of alcohols exhibit specific nanoordering inside cavities of metal–organic frameworks, thus creating unique environments with anomalous apparent polarity sensed by solutes.

Funder

Ministry of Science and Higher Education of the Russian Federation

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05724K

Reference74 articles.

1. Selective binding and removal of guests in a microporous metal–organic framework

2. A highly crystalline anthracene-based MOF-74 series featuring electrical conductivity and luminescence

3. Simultaneous determination of indoor ammonia pollution and its biological metabolite in the human body with a recyclable nanocrystalline lanthanide-functionalized MOF

4. A facile modular approach to the 2D oriented assembly MOF electrode for non-enzymatic sweat biosensors

5. Cooperative insertion of CO2 in diamine-appended metal-organic frameworks