The interconversion between THF·B3H7 and B3H8−: an efficient synthetic method for MB3H8 (M = Li and Na)

Author:

Liu Xin-Ran12345,Chen Xi-Meng12345,Zhang Jie12345ORCID,Jensen Torben R.6789ORCID,Chen Xuenian12345ORCID

Affiliation:

1. Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials

2. School of Chemistry and Chemical Engineering

3. Henan Normal University

4. Xinxiang

5. China

6. Center for Materials Crystallography (CMC) at the Department of Chemistry and the Interdisciplinary Nanoscience Center (iNANO)

7. Aarhus University

8. 8000 Aarhus

9. Denmark

Abstract

Efficient synthetic methods for Li/NaB3H8 have been developed based on the nucleophilicity of the B–H bonding pair electrons.

Funder

National Natural Science Foundation of China

Ministry of Education of the People's Republic of China

Danmarks Grundforskningsfond

Det Frie Forskningsråd

Carlsbergfondet

Danish Agency for Science and Higher Education

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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