An improved method for the synthesis and formation mechanism of M2B10H14 based on the reactions of B10H14 with MNH2BH3 (M = Na, K)-Reference-Cited by-同舟云学术

An improved method for the synthesis and formation mechanism of M₂B₁₀H₁₄ based on the reactions of B₁₀H₁₄ with MNH₂BH₃ (M = Na, K)

Published:2023 Issue:47 Volume:52 Page:17684-17688
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Chen Xi-Meng¹,Yu Xing-Chao¹,Chi Jing-Xian¹,Jing Yi²,Wang Hongju³,Zhang Na¹,Zhang Chen¹,Ge Yi-Wen¹,Chen Xuenian¹²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan 453007, China

2. College of Chemistry, Zhengzhou University, Zhengzhou, Henan 450001, China

3. School of Environment, Henan Normal University, Xinxiang, Henan 453007, China

Abstract

An improved method for the synthesis of M2B10H14 (M = Na and K) has been developed, and two possible formation mechanisms of the B10H142− anion were proposed, in which the NH2BH3− anion acts as a proton abstractor and a hydride donor.

Funder

National Natural Science Foundation of China

Henan Provincial Science and Technology Research Project

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT03403H

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5. Synthesis, Formation Mechanism, and Structure of K[BH₃S(CH₃)BH₃] and Its Application in Preparation of KB₃H₈