A novel method for the synthesis of solvent-free Mg(B3H8)2-Reference-Cited by-同舟云学术

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A novel method for the synthesis of solvent-free Mg(B3H8)2

Published:2016 Issue:9 Volume:45 Page:3687-3690
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Huang Jianmei¹²³⁴⁵,Yan Yigang⁶⁷⁸,Remhof Arndt⁶⁷⁸,Zhang Yucheng⁶⁷⁸,Rentsch Daniel⁶⁷⁸,Au Yuen S.⁹¹⁰¹¹¹²¹³,de Jongh Petra E.⁹¹⁰¹¹¹²¹³,Cuevas Fermin¹⁴¹⁵¹⁶,Ouyang Liuzhang¹²³⁴,Zhu Min¹²³⁴,Züttel Andreas⁵¹⁷¹⁸¹⁹⁸

Affiliation:

1. School of Materials Science and Engineering and Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials

2. South China University of Technology

3. 510641 Guangzhou

4. China

5. Institute of Chemical Sciences and Engineering (ISIC)

6. Empa-Swiss Federal Laboratories for Materials Science and Technology

7. 8600 Dübendorf

8. Switzerland

9. Inorganic Chemistry and Catalysis

10. Debye Institute for Nanomaterials Science

11. Utrecht University

12. Utrecht

13. The Netherlands

14. CMTR/ICMPE/CNRS UMR 7182

15. Thiais Cedex

16. France

17. École polytechnique fédérale de Lausanne (EPFL) Valais/Wallis

18. Energypolis

19. 1950 Sion

Abstract

A novel and solvent-free method for the synthesis of Mg(B₃H₈)₂ by a gas–solid reaction between B₂H₆ and Mg₂NiH₄ is presented.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04517G

Reference31 articles.

1. Volatile Magnesium Octahydrotriborate Complexes as Potential CVD Precursors to MgB2. Synthesis and Characterization of Mg(B3H8)2 and Its Etherates

2. A New Class of CVD Precursors to Metal Borides: Cr(B3H8)2 and Related Octahydrotriborate Complexes

3. New, systematic syntheses of boron hydrides via hydride ion abstraction reactions: preparation of B2H6, B4H10, B5H11, and B10H14

4. Mechanistic aspects of boron hydride reactions

5. Transition-metal-promoted oxidative fusion with carborane and borane anions. Synthesis of C4Bn (n = 8-11) carborane systems in the presence of B5H8- and B3H8- ions

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