Stabilisation of high-valent Cu3+ in a Keggin-type polyoxometalate-Reference-Cited by-同舟云学术

Stabilisation of high-valent Cu3+ in a Keggin-type polyoxometalate

Published:2020 Issue:15 Volume:56 Page:2324-2327
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Li Xiang¹²³⁴⁵^ORCID,Ren Yuanhang¹²³⁴⁵^ORCID,Weng Zhewei¹²³⁴⁵,Yue Bin¹²³⁴⁵^ORCID,He Heyong¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials

2. Collaborative Innovation Center of Chemistry for Energy Materials

3. Fudan University

4. Shanghai 200438

5. P. R. China

Abstract

A Cu³⁺-containing polyoxometalate is synthesized by using the Ag⁺-assisted peroxydisulfate oxidation method and the existence of Cu³⁺ is proven by characterization.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC09235H

Reference28 articles.

1. Oxidation of Nickel(II) and Manganese(II) by Peroxodisulfate in Aqueous Solution in the Presence of Molybdate. Crystal Structure of the (NH4)6[NiMo9O32].6H2O Product

2. The crystal structure of potassium nonamolybdomanganate(IV) hexahydrate, K6[MnMo9O32]·6H2O

3. Catalytic water oxidation based on Ag(i)-substituted Keggin polyoxotungstophosphate

4. A Waugh type [CoMo9O32]6− cluster with atomically dispersed CoIV originates from Anderson type [CoMo6O24]3− for photocatalytic oxygen molecule activation

5. Oxo transfer from high-valent totally inorganic oxometalloporphyrin analogs, [Xn+W11O39CrVO](9-n)- (Xn+ = P5+, Si4+), to hydrocarbons

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