A Waugh type [CoMo9O32]6− cluster with atomically dispersed CoIV originates from Anderson type [CoMo6O24]3− for photocatalytic oxygen molecule activation-Reference-Cited by-同舟云学术

A Waugh type [CoMo9O32]6− cluster with atomically dispersed CoIV originates from Anderson type [CoMo6O24]3− for photocatalytic oxygen molecule activation

Published:2017 Issue:40 Volume:9 Page:15332-15339
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Chen Yongdong¹²³⁴⁵,Zhang Chaolei¹²³⁴⁵,Yang Caoping¹²³⁴⁵,Zhang Jiangwei⁶⁷⁸⁹¹⁰^ORCID,Zheng Kai⁶⁷⁸⁹¹⁰,Fang Qihua⁶⁷⁸⁹¹⁰,Li Gao⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. The Center of New Energy Materials and Technology

2. College of Chemistry and Chemical Engineering

3. Southwest Petroleum University

4. Chengdu 610500

5. China

6. Gold Catalysis Research Center

7. State Key Laboratory of Catalysis

8. Dalian Institute of Chemical Physics

9. Chinese Academy of Sciences

10. Dalian 116023

Abstract

Photocatalytic ¹O₂ generation was detected by diverse light source irradiation employing a [CoMo₉O₃₂]⁶⁻ cluster with atomically dispersed Co^IV as a photosensitizer.

Funder

Natural Science Foundation of Liaoning Province

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2017/NR/C7NR04373B

Reference36 articles.

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3. Polyoxometalate-assisted synthesis of transition-metal cubane clusters as artificial mimics of the oxygen-evolving center of photosystem II