Catalytic water oxidation based on Ag(i)-substituted Keggin polyoxotungstophosphate-Reference-Cited by-同舟云学术

Catalytic water oxidation based on Ag(i)-substituted Keggin polyoxotungstophosphate

Published:2014 Issue:46 Volume:43 Page:17406-17415
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Cui Ying¹²³,Shi Lei¹²³,Yang Yanyi¹²³,You Wansheng¹²³,Zhang Lancui¹²³,Zhu Zaiming¹²³,Liu Meiying¹²³,Sun Licheng⁴⁵⁶

Affiliation:

1. Institute of Chemistry for Functionalized Materials

2. Liaoning Normal University

3. Dalian, P. R. China

4. State Key Laboratory of Fine Chemicals

5. Dalian University of Technology

6. Dalian 116024, P. R. China

Abstract

A Ag(i) complex formulated as [H₃Ag^I(H₂O)PW₁₁O₃₉]³⁻ is formed in aqueous solution. It can be oxidized by S₂O₈²⁻, dominantly generating a dark green Ag(ii) complex [H₃Ag^II(H₂O)PW₁₁O₃₉]²⁻ and a small amount of Ag(iii) complex [H₃Ag^IIIOPW₁₁O₃₉]³⁻, simultaneously evolving O₂.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01538J

Reference63 articles.

1. Solar Water Splitting Cells

2. Molecular Catalysts that Oxidize Water to Dioxygen

3. Electrocatalytic and photocatalytic water oxidation to dioxygen based on metal complexes

4. Molecular water-oxidation catalysts for photoelectrochemical cells

5. Catalytic oxidation of water by an oxo-bridged ruthenium dimer

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