Stabilization of Ni-containing Keggin-type polyoxometalates with variable oxidation states as novel catalysts for electrochemical water oxidation

Author:

Li Xiang1ORCID,Ng Bryan Kit Yue1ORCID,Ho Ping-Luen1ORCID,Jia Chunbo2,Shang Jining2,Yoskamtorn Tatchamapan1,Pan Xuelei1ORCID,Li Yiyang1ORCID,Li Guangchao1ORCID,Wu Tai-Sing3,Soo Yun-Liang3ORCID,He Heyong2ORCID,Yue Bin2ORCID,Tsang Shik Chi Edman1ORCID

Affiliation:

1. Department of Chemistry, University of Oxford, Oxford, OX1 3QR, UK

2. Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200438, China

3. National Synchrotron Radiation Research Center, 101 Hsin-Ann Road, Hsinchu 30076, Taiwan

Abstract

Stabilization of PW9Ni3 polyoxometalate (POM) anions in the MIL-101(Cr) framework, which displays high water oxidation activity under electrochemical conditions with the POM remaining intact.

Funder

Engineering and Physical Sciences Research Council

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

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