Heterobimetallic Dinitrogen Complexes That Contain the {[N3N]Mo−NN}- Ligand
Author:
Affiliation:
1. Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, and Department of Chemistry, Northeastern University, 360 Huntington Avenue, Boston, Massachusetts 02115
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic9811188
Reference36 articles.
1. Derivatization of Dinitrogen by Molybdenum in Triamidoamine Complexes
2. “Fixation” of Dinitrogen by Molybdenum and the Formation of a Trigonal Planar Iron−Tris[molybdenum(dinitrogen)] Complex
3. Synthesis and Decomposition of Alkyl Complexes of Molybdenum(IV) That Contain a [(Me3SiNCH2CH2)3N]3- Ligand. Direct Detection of α-Elimination Processes That Are More than Six Orders of Magnitude Faster than β-Elimination Processes
4. Synthesis and characterization of the homoleptic aryloxides [M{O(2,4,6-tert-Bu3C6H2)}2]2 (M = manganese, iron), the adducts [Mn(OCPh3)2(py)2] and [Fe(OCPh3)2(THF)2], and the mixed complex [Fe{N(SiMe3)2}{.mu.-O(2,4,6-tert-Bu3C6H2)}]2: evidence for primarily ionic metal-oxygen bonding
5. Three-coordinate iron complexes: x-ray structural characterization of the iron amide-bridged dimers [Fe(NR2)2]2 (R = SiMe3, C6H5) and the adduct Fe[N(SiMe3)2]2(THF) and determination of the association energy of the monomer Fe{N(SiMe3)2}2 in solution
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