Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides-Reference-Cited by-同舟云学术

Iron promoted end-on dinitrogen-bridging in heterobimetallic complexes of uranium and lanthanides

Published:2024 Issue:18 Volume:15 Page:6842-6852
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Jori Nadir¹^ORCID,Moreno Juan J.¹²^ORCID,Shivaraam R. A. Keerthi¹^ORCID,Rajeshkumar Thayalan³,Scopelliti Rosario¹^ORCID,Maron Laurent³^ORCID,Campos Jesús²^ORCID,Mazzanti Marinella¹^ORCID

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland

2. Departamento de Química Inorgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Instituto de Investigaciones Químicas (IIQ), Consejo Superior de Investigaciones Científicas (CSIC) and Universidad de Sevilla, 41092 Sevilla, Spain

3. Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077 Cedex 4, Toulouse, France

Abstract

End-on bridging dinitrogen binding to U(iii), Ln(iii) and Ln(ii) is favoured for the iron-bound N2 compared to free N2, resulting in increased N2 activation with increasing Ln Lewis acidity with a back-bonding contribution only found for U(iii).

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

FP7 People: Marie-Curie Actions

École Polytechnique Fédérale de Lausanne

Institut Universitaire de France

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01050G

Reference95 articles.

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4. Remarkable catalytic activity of dinitrogen-bridged dimolybdenum complexes bearing NHC-based PCP-pincer ligands toward nitrogen fixation

5. Recent advances in catalytic silylation of dinitrogen using transition metal complexes

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