Coordination of Al(C6F5)3vs. B(C6F5)3 on group 6 end-on dinitrogen complexes: chemical and structural divergences-Reference-Cited by-同舟云学术

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Coordination of Al(C₆F₅)₃vs. B(C₆F₅)₃ on group 6 end-on dinitrogen complexes: chemical and structural divergences

Published:2024 Issue:29 Volume:15 Page:11321-11336
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Escomel Léon¹^ORCID,Martins Frederico F.²^ORCID,Vendier Laure¹,Coffinet Anaïs¹,Queyriaux Nicolas¹^ORCID,Krewald Vera²^ORCID,Simonneau Antoine¹^ORCID

Affiliation:

1. LCC-CNRS, Université de Toulouse, CNRS, UPS 205 Route de Narbonne, BP44099, F-31077 Toulouse Cedex 4, France

2. Department of Chemistry, Quantum Chemistry, TU Darmstadt, Peter-Grünberg-Str. 4, 6, 4287 Darmstadt, Germany

Abstract

Group 6 metal/Al(C6F5)3 donor–acceptor systems for N2 activation surprisingly diverge from their B(C6F5)3 analogues, providing access to M{NN(Al(C6F5)3)}2 adducts. Implications for the N2 ligand are explored spectroscopically and computationally.

Funder

Agence Nationale de la Recherche

H2020 European Research Council

Centre National de la Recherche Scientifique

Ministère de l'Education Nationale, de l'Enseignement Supérieur et de la Recherche

Technische Universität Darmstadt

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC02713B

Reference99 articles.

1. Catalytic N2-to-NH3 (or -N2H4) Conversion by Well-Defined Molecular Coordination Complexes

2. Molecular Catalysts for N 2 Reduction: State of the Art, Mechanism, and Challenges

3. Donor‐Acceptor Activation of Carbon Dioxide

4. Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

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