Synthesis and Decomposition of Alkyl Complexes of Molybdenum(IV) That Contain a [(Me3SiNCH2CH2)3N]3- Ligand. Direct Detection of α-Elimination Processes That Are More than Six Orders of Magnitude Faster than β-Elimination Processes-Reference-Cited by-同舟云学术

Synthesis and Decomposition of Alkyl Complexes of Molybdenum(IV) That Contain a [(Me3SiNCH2CH2)3N]3- Ligand. Direct Detection of α-Elimination Processes That Are More than Six Orders of Magnitude Faster than β-Elimination Processes

Published:1997-12-01 Issue:49 Volume:119 Page:11876-11893
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Schrock Richard R.¹,Seidel Scott W.¹,Mösch-Zanetti Nadia C.¹,Shih Keng-Yu¹,O'Donoghue Myra B.¹,Davis William M.¹,Reiff William M.¹

Affiliation:

1. Contribution from the Departments of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, and Northeastern University, Boston, Massashusetts 02115

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja970697x

Reference55 articles.

1. Atranes: new examples with unexpected properties

2. Synthesis of vanadium and titanium complexes of the type RM[(Me3SiNCH2CH2)3N] (R = Cl, alkyl) and the structure of ClV[(Me3SiNCH2CH2)3N]

3. New azasilatranes: synthesis and substitution reactions

4. Synthesis of Molybdenum and Tungsten Complexes That Contain Triamidoamine Ligands of the Type (C6F5NCH2CH2)3N and Activation of Dinitrogen by Molybdenum

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