Nonclassical Organolanthanoid Metal Chemistry: [K([18]-crown-6)(η2-PhMe)2]X (X = [(LnCpt3)2(μ-H)], [(LnCp‘ ‘2)2(μ-η6:η6-PhMe)]) from [LnCpx3], K, and [18]-crown-6 in Toluene (Ln = La, Ce; Cpt = η5-C5H4SiMe2But; Cp‘ ‘ = η5-C5H3(SiMe3)2-1,3)
Author:
Affiliation:
1. The Chemistry Laboratory, University of Sussex, Brighton, U.K. BN1 9QJ
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om0001873
Reference11 articles.
1. First identification by EPR spectra of lanthanum(ii) organometallic intermediates (and E½ for La3+ → La2+) in the C–O bond activation of dimethoxyethane
2. Activation of a CO bond by reaction of a tris(cyclopentadienyl)lanthanide complex with an alkali metal in dimethoxyethane (DME); crystal structures of [Ndη-C5H3(SiMe3)2-1,32(μ-OMe)2Li(DME)] and [{Ce(η-C5H3tBu2-1,3)2(μ-OMe)2]
3. The first metal complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion); synthesis and structures of [K(18-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)](Ln = La, Ce)
4. Synthesis and Characterization of Organolanthanidocene(III) (Ln = La, Ce, Pr, Nd) Complexes Containing the 1,4-Cyclohexa-2,5-dienyl Ligand (Benzene 1,4-Dianion): Structures of [K([18]-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)] [Cp‘ ‘ = η5-C5H3(SiMe3)2-1,3; Ln = La, Ce, Nd]
5. The First Example of a Crystalline Subvalent Organolanthanum Complex: [K([18]crown-6)- (η2-C6H6)2][(LaCptt2)2(μ-η6:η6-C6H6)]•2C6H6 (Cptt = η5-C5H3But2-1,3)
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