Isolation and redox reactivity of cerium complexes in four redox states-Reference-Cited by-同舟云学术

Isolation and redox reactivity of cerium complexes in four redox states

Published:2023 Issue:22 Volume:14 Page:6011-6021
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hsueh Fang-Che¹^ORCID,Rajeshkumar Thayalan²,Maron Laurent²^ORCID,Scopelliti Rosario¹^ORCID,Sienkiewicz Andrzej³⁴^ORCID,Mazzanti Marinella¹^ORCID

Affiliation:

1. Group of Coordination Chemistry, Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland

2. Laboratoire de Physique et Chimie des Nano-objets, Institut National des Sciences Appliquées, 31077 Toulouse, Cedex 4, France

3. Laboratory for Quantum Magnetism, Institute of Physics, École Polytechnique Fédérale de Lausanne (EPFL), 1015, Lausanne, Switzerland

4. ADSresonances Sàrl, 1920 Martigny, Switzerland

Abstract

The tris-siloxide tripodal ligand stabilizes a cerium complex in four different oxidation states and allows the unprecedented two-electron reduction of Ce(iii) to yield masked Ce(i) enabling cerium based multielectron redox chemistry.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

École Polytechnique Fédérale de Lausanne

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC01478A

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