The First Example of a Crystalline Subvalent Organolanthanum Complex: [K([18]crown-6)- (η2-C6H6)2][(LaCptt2)2(μ-η6:η6-C6H6)]•2C6H6 (Cptt = η5-C5H3But2-1,3)
Author:
Affiliation:
1. The Chemistry Laboratory University of Sussex, Brighton, BN1 9QJ, UK The Chemistry Department, University of Warwick Coventry, CV4 7AL, UK
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja980377t
Reference15 articles.
1. First identification by EPR spectra of lanthanum(ii) organometallic intermediates (and E½ for La3+ → La2+) in the C–O bond activation of dimethoxyethane
2. The first metal complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion); synthesis and structures of [K(18-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)](Ln = La, Ce)
3. Synthesis and Structure of the First Molecular Thulium(II) Complex:[TmI2(MeOCH2CH2OMe)3]
4. New 7r-cyclooctate'I'raenyl and iT-cyclopentadienyl complexes of cerium
5. Nichtklassische organolanthanoid(II)komplexe: Darstellung und reaktivität der ersten organoneodym(II)verbindung
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