Reductive C–O Cleavage of Ethereal Solvents and 18-Crown-6 in Ln(NR2)3/KC8Reactions (R = SiMe3)
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025, United States
Funder
Division of Chemistry
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.3c00689
Reference78 articles.
1. Activation of a CO bond by reaction of a tris(cyclopentadienyl)lanthanide complex with an alkali metal in dimethoxyethane (DME); crystal structures of [Ndη-C5H3(SiMe3)2-1,32(μ-OMe)2Li(DME)] and [{Ce(η-C5H3tBu2-1,3)2(μ-OMe)2]
2. The first metal complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion); synthesis and structures of [K(18-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)](Ln = La, Ce)
3. First identification by EPR spectra of lanthanum(ii) organometallic intermediates (and E½ for La3+ → La2+) in the C–O bond activation of dimethoxyethane
4. The First Example of a Crystalline Subvalent Organolanthanum Complex: [K([18]crown-6)- (η2-C6H6)2][(LaCptt2)2(μ-η6:η6-C6H6)]•2C6H6 (Cptt = η5-C5H3But2-1,3)
5. Synthesis and Characterization of Organolanthanidocene(III) (Ln = La, Ce, Pr, Nd) Complexes Containing the 1,4-Cyclohexa-2,5-dienyl Ligand (Benzene 1,4-Dianion): Structures of [K([18]-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)] [Cp‘ ‘ = η5-C5H3(SiMe3)2-1,3; Ln = La, Ce, Nd]
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