Silyl Hydrides of Tantalum Supported by Cyclopentadienyl-imido Ligand Sets: Syntheses, X-ray, NMR, and DFT Studies-Reference-Cited by-同舟云学术

Silyl Hydrides of Tantalum Supported by Cyclopentadienyl-imido Ligand Sets: Syntheses, X-ray, NMR, and DFT Studies

Published:2008-10-15 Issue:22 Volume:27 Page:5968-5977
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Ignatov Stanislav K.¹,Rees Nicholas H.¹,Merkoulov Alexei A.¹,Dubberley Stuart R.¹,Razuvaev Alexei G.¹,Mountford Philip¹,Nikonov Georgii I.¹

Affiliation:

1. Department of Chemistry, Nizhny Novgorod State University, Gagarin Avenue 23, 603600 Nizhny Novgorod, Russian Federation, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, U.K., Department of Chemistry, Moscow State University, Vorob’evy Gory, 119992, Moscow, Russian Federation, and Department of Chemistry, Brock University, Glenridge Avenue 500, St. Catharines, ON L2S 3A1, Canada

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om800553y

Reference76 articles.

1. The Search for New-Generation Olefin Polymerization Catalysts: Life beyond Metallocenes

2. Advances in Non-Metallocene Olefin Polymerization Catalysis

3. Synthesis and Reactivity of Alkyl, Hydride, and Silyl Derivatives of the (Terphenyl)imido Fragments Cp*(ArMesN)Ta (Cp* = η5-C5Me5; ArMes = 2,6-(2,4,6-Me3C6H2)2C6H3) and Cp*(ArTripN)Ta (ArTrip = 2,6-(2,4,6-iPr3C6H2)2C6H3)

4. Tantalum Alkyl and Silyl Complexes of the Bulky (Terphenyl)imido Ligand [2,6-(2,4,6-Me3C6H2)2C6H3N]2- ([Ar*N]2-). Generation and Reactivity of [(Ar*N)(Ar*NH)Ta(H)(OSO2CF3)], Which Reversibly Transfers Hydride to an Aromatic Ring of the Arylamide Ligand

5. Neutral and Anionic Silyl Hydride Derivatives of the Tantalum Imido Fragment Cp*(DippN)Ta (Cp* = η5-C5Me5; Dipp = 2,6-iPr2C6H3). Reactive σ-Bonds and Intramolecular C−H Bond Activations Involving the Silyl Ligands

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