NHC carbene supported half-sandwich hydridosilyl complexes of ruthenium: the impact of supporting ligands on Si⋯H interligand interactions-Reference-Cited by-同舟云学术

NHC carbene supported half-sandwich hydridosilyl complexes of ruthenium: the impact of supporting ligands on Si⋯H interligand interactions

Published:2016 Issue:1 Volume:45 Page:208-215
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Mai Van Hung¹²³⁴,Kuzmina Lyudmila G.⁵⁶⁷,Churakov Andrei V.⁵⁶⁷,Korobkov Ilia⁸⁹¹⁰¹¹¹²,Howard Judith A. K.¹¹³¹⁴¹⁵,Nikonov Georgii I.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Brock University

3. 1812 Sir Isaac Brock Way

4. Canada

5. N. S. Kurnakov Institute of General and Inorganic Chemistry

6. Moscow

7. Russia

8. X-Ray Core Facility

9. Faculty of Science

10. University of Ottawa

11. Ottawa

12. Canada K1N 6N5

13. University of Durham

14. Durham

15. UK

Abstract

Electron donating NHC carbene ligand IPr exerts stronger RuH⋯Si interactions in complexes Cp(IPr)RuH₂(SiR₃) than in related ⁱPr₃P complexes Cp(ⁱPr₃P)RuH₂(SiR₃).

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04067A

Reference65 articles.

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3. Alkyne Hydrosilylation Catalyzed by a Cationic Ruthenium Complex: Efficient and General Trans Addition

4. Markovnikov Alkyne Hydrosilylation Catalyzed by Ruthenium Complexes

5. Synthetic Stitching with Silicon: Geminal Alkylation−Hydroxylation of Alkynyl Carbonyl Compounds

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