Hydridosilylamido complexes of Ta and Mo isolobal with Berry's zirconocenes: syntheses, β-Si–H agostic interactions, catalytic hydrosilylation, and insight into mechanism-Reference-Cited by-同舟云学术

Hydridosilylamido complexes of Ta and Mo isolobal with Berry's zirconocenes: syntheses, β-Si–H agostic interactions, catalytic hydrosilylation, and insight into mechanism

Published:2016 Issue:6 Volume:45 Page:2554-2561
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

McLeod Nicolas A.¹²³⁴,Kuzmina Lyudmila G.⁵⁶⁷,Korobkov Ilia⁸⁹¹⁰¹¹⁴,Howard Judith A. K.¹²¹³¹⁴¹⁵,Nikonov Georgii I.¹²³⁴

Affiliation:

1. Chemistry Department

2. Brock University

3. St. Catharines

4. Canada

5. N. S. Kurnakov Institute of General and Inorganic Chemistry

6. Moscow

7. Russia

8. X-Ray Core Facility

9. Faculty of Science

10. University of Ottawa

11. Ottawa

12. Department of Chemistry

13. University of Durham

14. Durham

15. UK

Abstract

The β-SiH agostic complex (ArN)₂Mo{η³-N(^tBu)SiMe₂–H}H is a pre-catalyst for hydrosilylation of carbonyls. Mechanistic studies revealed a non-hydride mechanism, with the benzoxy complex 8 being the resting state.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04548G

Reference77 articles.

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3. Metal–dihydrogen and σ-bond coordination: the consummate extension of the Dewar–Chatt–Duncanson model for metal–olefin π bonding

4. Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

5. Structural and bonding characteristics in transition metal–silane complexes

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