Synthesis of NPN-Coordinated Tantalum Alkyl Complexes and Their Hydrogenolysis: Isolation of a Terminal Tantalum Hydride Incorporating a Doubly Cyclometalated NPN Scaffold-Reference-Cited by-同舟云学术

Synthesis of NPN-Coordinated Tantalum Alkyl Complexes and Their Hydrogenolysis: Isolation of a Terminal Tantalum Hydride Incorporating a Doubly Cyclometalated NPN Scaffold

Published:2017-04-20 Issue:9 Volume:56 Page:5122-5134
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Batke Sonja¹,Sietzen Malte¹,Wadepohl Hubert¹,Ballmann Joachim¹^ORCID

Affiliation:

1. Anorganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 276, 69120 Heidelberg, Germany

Funder

Deutsche Forschungsgemeinschaft

Verband der Chemischen Industrie

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.inorgchem.7b00277

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1. 955. The di-π-cyclopentadienyl hydrides of tantalum, molybdenum, and tungsten

2. Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands?

3. Kinetics and mechanism of the insertion of olefins into niobium- and tantalum-hydride bonds: a study of the competition between steric and electronic effects

4. X-ray crystal structure determination of [.eta.5-C5(CH3)5]Ta[P(CH3)3]2H4 and high-field NMR studies of phosphine derivatives of (pentamethylcyclopentadienyl)tantalum(V) hydrides

5. Reduction of carbon monoxide by binuclear tantalum hydride complexes

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4. Synthetic and Computational Studies on the Thermal and Photochemical Reactions of [NPN]TaMe3 (NPN = PhP(CH2SiMe2NPh)2) and [MesNPN]TaMe3 (MesNPN = PhP(CH2SiMe2N(2,4,6-Me3C6H2))2);Organometallics;2017-09-07