Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 4. Decarbonylation Reactions of [M2(η5-C5H5)2(CO)4{μ-(EtO)2POP(OEt)2}] (M = Mo, W)
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica, IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain
2. Laboratoire de Chimie des Métaux de Transition, UACNRS 419, Université P. et M. Curie, 4 Place Jussieu, 75252 Paris, Cedex 05, France
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om961036w
Reference34 articles.
1. Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 1. Decarbonylation Reactions of [W2(η5-C5H5)2(CO)4(μ-R2PCH2PR2)] (R = Ph, Me)
2. Reversible intramolecular carbon-hydrogen oxidative addition of cyclopentadienyl ligands at ditungsten(I) centers. A general intermediate step in the way to unsaturated dimetal cyclopentadienyl carbonyl complexes?
3. Synthesis and reactivity of the unsaturated dimolybdenum compound [Mo2(η-C5H5)2(μ-CH2PPh2)(μ-PPh2)(CO)2]. Crystal structure of [Mo2(η-C5H5)2(μ-I)(μ-CH2PPh2)- (μ-PPh2)(CO)2][TlI4]·CH2Cl2
4. Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 3. Decarbonylation Reactions of [MoW(η5-C5H5)2(CO)4(μ-Ph2PCH2PPh2)]
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