Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 1. Decarbonylation Reactions of [W2(η5-C5H5)2(CO)4(μ-R2PCH2PR2)] (R = Ph, Me)-Reference-Cited by-同舟云学术

Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 1. Decarbonylation Reactions of [W2(η5-C5H5)2(CO)4(μ-R2PCH2PR2)] (R = Ph, Me)

Published:1997-02-01 Issue:3 Volume:16 Page:354-364
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Alvarez M. Angeles¹,García M. Esther¹,Riera Víctor¹,Ruiz Miguel A.¹,Falvello Larry R.²,Bois Claudette³

Affiliation:

1. Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, 33071 Oviedo, Spain

2. Departamento de Química Inorgánica, Universidad de Zaragoza, 50009 Zaragoza, Spain

3. Laboratoire de Chimie des Métaux de Transition, UACNRS 419, Université P. et M. Curie, 4 Place Jussieu, 75252 Paris, cedex 05, France

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om960714b

Reference71 articles.

1. Unsaturated Dimetal Cyclopentadienyl Carbonyl Complexes

2. Reactions of the metal-metal triple bond in Cp2Mo2(CO)4 and related complexes

3. Linear semibridging carbonyls. 4. A consequence of steric crowding and strong metal-to-metal bonding

4. Synthesis and reactivity of the unsaturated dimolybdenum compound [Mo2(η-C5H5)2(μ-CH2PPh2)(μ-PPh2)(CO)2]. Crystal structure of [Mo2(η-C5H5)2(μ-I)(μ-CH2PPh2)- (μ-PPh2)(CO)2][TlI4]·CH2Cl2

5. Reversible intramolecular carbon-hydrogen oxidative addition of cyclopentadienyl ligands at ditungsten(I) centers. A general intermediate step in the way to unsaturated dimetal cyclopentadienyl carbonyl complexes?

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