Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study-Reference-Cited by-同舟云学术

Terminal vs. bridging coordination of CO and NO ligands after decarbonylation of [W2Cp2(μ-PR2)(CO)3(NO)] complexes (R = Ph, Cy). An experimental and computational study

Published:2017 Issue:31 Volume:46 Page:10440-10451
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Alvarez M. Angeles¹²³⁴,García M. Esther¹²³⁴^ORCID,García-Vivó Daniel¹²³⁴^ORCID,Rueda M. Teresa¹²³⁴,Ruiz Miguel A.¹²³⁴^ORCID,Toyos Adrián¹²³⁴,Vega M. Fernanda¹²³⁴

Affiliation:

1. Departamento de Química Orgánica e Inorgánica/IUQOEM

2. Universidad de Oviedo

3. E-33071 Oviedo

4. Spain

Abstract

Photolysis of the title complexes yields κ¹:η²-CO-bridged derivatives, and not their unsaturated κ¹:κ¹-NO-bridged isomers, despite their similar thermodynamic stability.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02243C

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