Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 3. Decarbonylation Reactions of [MoW(η5-C5H5)2(CO)4(μ-Ph2PCH2PPh2)]
Author:
Affiliation:
1. Departamento de Química Orgánica e Inorgánica/IUQOEM, Universidad de Oviedo, E-33071 Oviedo, Spain
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om960920j
Reference27 articles.
1. Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 1. Decarbonylation Reactions of [W2(η5-C5H5)2(CO)4(μ-R2PCH2PR2)] (R = Ph, Me)
2. Reversible intramolecular carbon-hydrogen oxidative addition of cyclopentadienyl ligands at ditungsten(I) centers. A general intermediate step in the way to unsaturated dimetal cyclopentadienyl carbonyl complexes?
3. Oxidative Additions of Coordinated Ligands at Unsaturated Molybdenum and Tungsten Diphosphine-Bridged Carbonyl Dimers. 2. Decarbonylation Reactions of [Mo2(η5-C5H4R)2(CO)4(μ-Ph2PCH2PPh2)] (R = H, Me)
4. Synthesis and reactivity of the unsaturated dimolybdenum compound [Mo2(η-C5H5)2(μ-CH2PPh2)(μ-PPh2)(CO)2]. Crystal structure of [Mo2(η-C5H5)2(μ-I)(μ-CH2PPh2)- (μ-PPh2)(CO)2][TlI4]·CH2Cl2
5. C-H Cleavages in the Photoreactions of [M2(.eta.5-C5H5)2(CO)6] (M = Mo, W): Isolation and Characterization of the V-Shaped Trinuclear Clusters [M2M'(.mu.-.eta.1,.eta.5-C5H4)(.eta.5-C5H5)2(CO)6] (M, M' = Mo or W)
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