Binding Nucleophiles to [Fe4Y4Cl4]2− (Y = S or Se) can Increase or Suppress the Rate of Proton Transfer to the Cluster
Author:
Affiliation:
1. Chemistry, School of Natural Sciences, Newcastle University, Newcastle upon Tyne, NE1 7RU, U.K.
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic800142e
Reference42 articles.
1. Protonenübertragung, Säure-Base-Katalyse und enzymatische Hydrolyse. Teil I: Elementarvorgänge
2. Proton Transfer, Acid-Base Catalysis, and Enzymatic Hydrolysis. Part I: ELEMENTARY PROCESSES
3. The Proton in Chemistry
4. Protonation of Unsaturated Hydrocarbon Ligands: Regioselectivity, Stereoselectivity, and Product Specificity
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1. Structural insight into halide-coordinated [Fe4S4XnY4−n]2− clusters (X, Y = Cl, Br, I) by XRD and Mössbauer spectroscopy;Dalton Transactions;2023
2. X-ray crystal structures of [NHR3]2[Fe4S4X4] (X = PhS, R = Et or n Bu; X = Cl, R = n Bu): implications for sites of protonation in Fe–S clusters;Transition Metal Chemistry;2016-04-21
3. Exploring the acid-catalyzed substitution mechanism of [Fe4S4Cl4]2−;Dalton Transactions;2016
4. Binding small molecules and ions to [Fe4S4Cl4]2− modulates rate of protonation of the cluster;Dalton Transactions;2016
5. Binding Substrates to Synthetic Fe-S-Based Clusters and the Possible Relevance to Nitrogenases;Bioinspired Catalysis;2014-08-22
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