Exploring the acid-catalyzed substitution mechanism of [Fe4S4Cl4]2−-Reference-Cited by-同舟云学术

Exploring the acid-catalyzed substitution mechanism of [Fe4S4Cl4]2−

Published:2016 Issue:1 Volume:45 Page:307-314
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Al-Rammahi Thaer M. M.¹²³⁴⁵,Henderson Richard A.¹²³⁴

Affiliation:

1. School of Chemistry

2. Newcastle University

3. Newcastle upon Tyne

4. UK

5. Department of Chemistry

Abstract

Kinetic studies focussing on either the protonation or substitution step of the acid catalyzed substitution reactions of [Fe₄S₄Cl₄]²⁻ support a mechanism involving concomitant cluster protonation and Fe–(μ₃-SH) bond cleavage.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04008F

Reference29 articles.

1. Structural and Functional Aspects of Metal Sites in Biology

2. Aconitase as Iron−Sulfur Protein, Enzyme, and Iron-Regulatory Protein

3. Mechanism of Molybdenum Nitrogenase

4. Structural Basis of Biological Nitrogen Fixation

5. Evidence for Interstitial Carbon in Nitrogenase FeMo Cofactor

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