Binding small molecules and ions to [Fe4S4Cl4]2− modulates rate of protonation of the cluster
Author:
Affiliation:
1. School of Chemistry
2. Newcastle University
3. Newcastle upon Tyne
4. UK
5. Department of Chemistry
Abstract
Binding various small molecules and ions (Cl−, N3−, NCS−, substituted hydrazines, ButNC or pyridine) to [Fe4S4Cl4]2− facilitates the subsequent protonation of the cluster.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT04523A
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1. X-ray crystal structures of [NHR3]2[Fe4S4X4] (X = PhS, R = Et or n Bu; X = Cl, R = n Bu): implications for sites of protonation in Fe–S clusters;Transition Metal Chemistry;2016-04-21
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