Structural insight into halide-coordinated [Fe4S4XnY4−n]2− clusters (X, Y = Cl, Br, I) by XRD and Mössbauer spectroscopy-Reference-Cited by-同舟云学术

Structural insight into halide-coordinated [Fe₄S₄X_nY_4−n]²⁻ clusters (X, Y = Cl, Br, I) by XRD and Mössbauer spectroscopy

Published:2023 Issue:5 Volume:52 Page:1277-1290
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schüren Andreas O.¹²,Ridgway Benjamin M.²^ORCID,Di Salvo Florencia²³^ORCID,Carella Luca M.⁴,Gramm Verena K.¹,Metzger Elisa⁵,Doctorovich Fabio²³^ORCID,Rentschler Eva⁴^ORCID,Schünemann Volker⁵^ORCID,Ruschewitz Uwe¹^ORCID,Klein Axel¹^ORCID

Affiliation:

1. Universität zu Köln, Mathematisch-Naturwissenschaftliche Fakultät, Department für Chemie, Institut für Anorganische Chemie, Greinstraße 6, D-50939 Köln, Germany

2. INQUIMAE-CONICET-Universidad de Buenos Aires, Intendente Güiraldes 2160, Pabellón 2, Piso 3, C1428EGA, Buenos Aires, Argentina

3. Universidad de Buenos Aires, Facultad de Ciencias Exactas y Naturales, Departamento de Química Inorgánica, Analítica y Química Física, Intendente Güiraldes 2160, Pabellón 2, Piso 3, C1428EGA, Buenos Aires, Argentina

4. Johannes Gutenberg Universität Mainz, Department Chemie, Duesbergweg 10-14, 55128 Mainz, Germany

5. TU Kaiserlautern Department of Physics, 67663 Kaiserlautern, Germany

Abstract

Single crystal XRD at 298 and 173 K, magnetic measurements from 2 to 300 K and 57Fe Mössbauer spectroscopy of (BTMA)2[Fe4S4X2Y2] (X, Y = Cl, Br, or I) showed that the variation of X and Y had no effect on the delocalisation of Fe2.5+/Fe2.5+ in the clusters.

Funder

Deutscher Akademischer Austauschdienst

Consejo Nacional de Investigaciones Científicas y Técnicas

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03203A

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