Palladacycle-Promoted Solvolytic Cleavage of O,O-Dimethyl O-Aryl Phosphorothioates. Converting a Phosphorane-Like Transition State to an Observable Intermediate-Reference-Cited by-同舟云学术

Palladacycle-Promoted Solvolytic Cleavage of O,O-Dimethyl O-Aryl Phosphorothioates. Converting a Phosphorane-Like Transition State to an Observable Intermediate

Published:2011-07-11 Issue:16 Volume:50 Page:7852-7862
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Liu C. Tony¹,Neverov Alexei A.¹,Brown R. Stan¹

Affiliation:

1. Department of Chemistry, Queen’s University, Kingston, Ontario K7L 3N6, Canada

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic201062h

Reference45 articles.

1. Toy, A. D. F.; Walsh, E. N.InPhosphorus Chemistry in Everyday Living;2nd ed.American Chemical Society:Washington, DC, 1987; pp18–20;

2. Quin, L. D.InA Guide to Organophosphorus Chemistry;Wiley:New York, 2000; pp367–371.

3. Billion-fold Acceleration of the Methanolysis of Paraoxon Promoted by La(OTf)3 in Methanol

4. La3+-catalyzed methanolysis of O,O-diethyl S-(p-nitrophenyl) phosphorothioate and O,O-diethyl S-phenyl phosphorothioate. Millions-fold acceleration of the destruction of V-agent simulants

5. Zn2+-Catalyzed Methanolysis of Phosphate Triesters: A Process for Catalytic Degradation of the Organophosphorus Pesticides Paraoxon and Fenitrothion

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