Cu(II)-Promoted Methanolysis of N,N-Dipicolylacetamide. Multistep Activation by Decoupling of >N̈–C═O Resonance via Cu(II)–N Binding, Delivery of the Cu(II):(−OCH3) Nucleophile, and Metal Ion Assistance of the Departure of the Leaving Group
Author:
Affiliation:
1. Department of Chemistry, Queen’s University, Kingston, Ontario, Canada K7L 3N6
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo300329x
Reference25 articles.
1. Brown, R. S.InProgress in Inorganic Chemistry;Karlin, K., Ed.John Wiley and Sons:New York, 2011; Vol.57, p55and references therein.
2. Demonstration of Prominent Cu(II)-Promoted Leaving Group Stabilization of the Cleavage of a Homologous Set of Phosphate Mono-, Di-, and Triesters in Methanol
3. Catalysis of the Methanolysis of Activated Amides by Divalent and Trivalent Metal Ions. The Effect of Zn2+, Co2+, and La3+ on the Methanolysis of Acetylimidazole and Its (NH3)5CoIII Complex
4. Methanolysis of Thioamide Promoted by a Simple Palladacycle Is Accelerated by 108 over the Methoxide-Catalyzed Reaction
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